Players should also take note that some of the Most Wanted side quests will not become available until after you pass a certain point in the City of Fear main quest line. This includes Armored and Dangerous, Campaign for Disarmament, Creature of the Night, Friend in Need, Gotham on Fire, Gunrunner, Heir to the Cowl, Lamb to the Slaughter, The Line of Duty, Occupy Gotham, Own the Roads, The Perfect Crime, Riddler’s Revenge, and Two-Faced Bandit. This page will act as the main walkthrough for all 14 of the Most Wanted side missions in Batman: Arkham Knight.
